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Date: 20 May 2018
Carbon-Nanotube Memory that Really Competes  

Topic Name: Carbon-Nanotube Memory that Really Competes
Category: Nanobiotechnology
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Research persons: Päivi Törmä

Location: Helsinki, Finland


Carbon-Nanotube Memory that Really Competes

Researchers in Finland have created a form of carbon-nanotube based
information storage that is comparable in speed to a type of memory commonly
used in memory cards and USB "jump" drives.

The group's memory scheme has a write-erase time of 100 nanoseconds, which is
about 100,000 times faster than previously reported carbon-nanotube memory, and
retains this ability over more than 10,000 write-erase cycles. The work is
reported in the January 16, 2009, online edition of Nano Letters.

"In terms of speed and endurance, our memory structure is as good as the
commercially available Flash memory technologies," said Helsinki University of
Technology physicist Päivi Törmä

The memory scheme stores information using single-walled carbon-nanotube
transistors, specifically field-effect transistors, which are among the fastest
carbon-nanotube electrical components. Each transistor consists of four key
parts, the gate, source, drain, and substrate.

As a substrate, Törmä and her colleagues chose a silicon wafer. In collaboration
with Finnish technology-equipment company Beneq Oy, they applied a
20-nanometer-thick layer of hafnium oxide using atomic layer deposition, a
technique used to deposit materials in very thin layers. The hafnium oxide
separates the substrate, which was also used as the gate in this case, from the
rest of the structure. Choosing hafnium dioxide as the gate "dielectric"
material—an insulator placed between two conductors to separate them—appears to
be the key to the device's fast operation, as it can trap and release charge
very quickly and efficiently.

On top of the hafnium-oxide layer, the group deposited a few drops of a carbon-nanotube
solution, produced using commercially available nanotubes with diameters between
1.2 and 1.5 nanometers and lengths of 100 to 360 nanometers. Using an atomic
force microscope, they identified nanotubes with the proper alignment; only
those nanotubes became transistors. They then created source and drain
electrodes for each nanotube using the metal palladium, with the nanotube
forming the transistor's conductive channel.

Finally, the researchers deposited another 20-nanometer layer of hafnium oxide
on top of the nanotube transistor, to "passivate" the surface, preventing
unwanted reactions.

"The fast memory operation we have demonstrated could potentially also be
realized using other carbon materials, such as carbon-nanotube bundles or
graphene," said Törmä.

Each transistor stores information based on whether current is running through
it. When the voltage applied across the transistor reaches a certain threshold,
current flows, which can represent one bit of information, either a "0" or a "1"
(bit is short for binary digit). For example, when the transistor is conducting
it may represent a "1," and when not conducting, a "0."

Each transistor can store information for about 150,000 seconds, or about 42
hours. This is quite short, although Törmä and her group think they can improve
it by adding an oxide layer between the gate and the nanotube.
In Figure: A side-view schematic of the single-walled carbon-nanotube
field-effect transistor, showing the two halfnium dioxide layers (HfO2). The
nanotube is represented by the honeycomb pattern in the center of the figure.
VGS is the voltage across the transistor's gate and source.

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